Advanced Nano-materialNanodiamonds

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What is Nanodiamond?

  • Graphical Image of a nanodiamond
  • Nanodiamond structure and surface chemistry
  • TEM Image of Nanodiamonds

Nanodiamonds are one of the most advanced carbon materials in the world.
Diamonds are renowned for their superlative physical qualities such as the highest hardness on earth, superior thermal conductivity to any bulk material, and the high refractive index and abbe number. Nanodiamonds are not only small-sized diamonds with the above features but they also could generate other functions owing to their nano size, various functional groups, high dispersibility, ζ potential, and amorphous carbon.

The structure of nanodiamonds consists of a diamond core and amorphous carbon layers. In more complex terms, each particle of nanodiamonds has sp³ bonded carbon atoms covered by sp². The most unique feature of nanodiamonds is the existence of various oxygenic functional groups on the surface, thus nanodiamonds have ζ potential in water.
The ζ potential disperses nanodiamonds uniformly and stably in water. Daicel also achieved dispersal of nanodiamonds in various organic solvents such as IPA, THF, MIBK, and Toluene by modifying surface chemicals on nanodiamonds.

Nanodiamonds are produced by a detonation method and the diamonds synthesized are extremely tiny particles with average diameter between 4~6nm.  The particles are almost spherical (precisely,  polyhedron) unlike abrasive diamonds for lapping, horning and polishing. Because of the size and the shape,  a specific surface area of a nanodiamond particle is over 300m²/g.

Nanodiamonds can be used in unique applications compared to other nano materials such as nano-silica, graphene, carbon nanotubes, fullerenes, and carbon nanohorns.
Potential applications of nanodiamonds are break-in additives for lubricants, antioxidants, grain refining agent, bio imaging, drug delivery, diamond sensors, and others. Each function of nanodiamonds in the applications is remarkably unique. 

Nanodiamonds can be a game-changing material of the future for those applications, with many products, and potential uses. 

Unique Properties of Nanodiamonds

Surface Chemistry

1

There are various of oxygenic functional groups on the nanodiamond surface. The main ones are carboxyl, hydroxyl, ketone, and ether. The total number of oxygenic functional groups on a nanodiamond reaches into the hundreds.

The oxygenic functional groups have a high affinity for water and polar organic solvents. On the other hand, they don’t have any affinity for oil or nonpolar solvents. Nanodiamonds agglomerate immediately in such media.

Daicel can offer solutions to the problem. Surface chemistries are controllable because of Daicel’s organic chemical technology, which makes it possible to realize a rich selection of organic solvent dispersions of nanodiamonds.

The line-up of nanodiamonds will be beneficial to users who hope to mix, disperse in raw materials such as plastics, oils, rubber, metal and others.

Original surface chemistry on a nanodiamond, Chemically modified surface chemistry on a nanodiamond
nanodiamond containing lubricants nanodiamonds metal plating composite nanodiamonds polymer composite

ζ potential

2

Nanodiamonds have ζ potential in dispersions.
The scientific technical term for colloidal dispersion means an electric potential of dispersed particles.
The ζ potential disperses nanodiamonds uniformly and stables in water and some organic polar solvents.

ζ potential of Nanodiamonds

Size

3

The nanodiamond particle is remarkably small, 4~6nm(four to six billionths of one meter).
The particle size is 20 times smaller than a virus. It is invisible to the naked eye.
A nanodiamond is the smallest diamond but an authentic one.

Size of Nanodiamond

Particle Numbers

4

There are about 900 quadrillion particles(9×1017) in 1 carat of nanodiamonds. 
In cases where surface activity is key to a function, the astronomical particle numbers (and also specific surface area) of monodispersed particles can be beneficial.

  • 1particle/carat

    Particle number of single diamond per 1carat
  • 9×1017particle/carat

    Particle numbers of nanodiamonds per 1carat

Specific Surface Area

5

One of the greatest properties of nanomaterials is their specific surface area.
Nanodiamonds have far larger surface areas than larger diamonds of equal mass.
When mono-dispersed nanodiamonds are used for applications where it is important to have contact with surrounding materials and create vast interfaces, functions can be maximized.

  • Diamonds

    Comparison of surface area between single diamond and nanodiamonds

    One 4cm Particle

  • 10 million times Total Surface Area 10 million times Total Surface Area
  • Nanodiamonds

    Comparison of surface area between single diamond and nanodiamonds

    All 4nm Particles
    (Same volume as 4cm particle)

Synthesis Technique of Single Digit Nanodiamonds

(Detonation Method)

Nanodiamonds are produced from explosives by detonation method followed by purification and dispersion processes as below. Daicel Corporation has installed a semicommercial facility for detonation process in our Harima Plant (Hyogo, Japan).
A Diamond structure is formed from carbon atoms in explosives(a mixture of TNT and RDX ) at very high temperature and pressure by detonation in a closed chamber.
Nanodiamonds are originally obtained as aggregates. It is expected that diamond properties will be more prominently expressed when the aggregates are further disintegrated into primary particles. Daicel has developed the single digit nanodiamonds(SDND).

Synthesis process of nanodiamonds

Fundamental Characteristics

Nanodiamonds have unique fundamental characteristics. Each characteristic contributes to applications functions.

  • Modify Surfaces

    Modify Surfaces

    One of most typical use of diamonds is abrasives. Nanodiamonds can polish objects and planarize atomically. Furthermore, chemical modification is also conducted by the tiny particles. Friction with nanodiamonds has oxidizability to some materials such as metals and ceramics.

    Running-in Additive( Friction Modifier, Anti-wear agent)
  • Suppress Degradation

    Suppress Degradation

    Well dispersed nanodiamonds suppress degradation of engineering plastics, oil and rubber. Basic mechanism of the function is  radical scavenging.

    Antioxidants, Thermal Stabilizer, Grain Refining Agent
  • Support Substance

    Support Substance

    Various chemicals (e.g.fluorescently labeled drugs, medicines, antibodies) can be attached onto nanodiamonds. Many researchers report that nanodiamonds work as drug delivery carriers with high safety to a living body because of the almost spherical shape of nanodiamonds.

    Drug delivery carrier

  • Conduct Electricity

    Conduct Electricity

    Insulators such as plastics and rubber could be turned into  electrical conductors by dispersing nanodiamonds  into them. (Tunnel effect)

Sample Line-up

  1. 1,Cluster Nanodiamonds(NDs) powder 1g
  2. 2,Water dispersion of ζ- NDs 1wt% 50ml
  3. 3,Water dispersion of ζ+ NDs 1wt% 50ml
  4. 4,Water dispersion of polyglycerol-grafted(polyglycerin modified)NDs 1wt% 10ml
  5. 5,THF dispersion of acrylated NDs 1wt% 10ml
  6. 6,IPA dispersion of modified NDs 1wt% 10ml
  7. 7,MIBK dispersion of modified NDs 1wt% 10ml
  8. 8,Toluene dispersion of modified NDs 1wt% 10ml

Contact

Daicel Corporation

Advanced Material Planning, R&D Headquarters
JR Shinagawa East Bldg., 2-18-1, Konan, Minato-ku, Tokyo, Japan
Email : nanodiamond_samples@jp.daicel.com
TEL : +81-3-6711-8162