Nanodiamonds
(DINNOVARE)

What is Nanodiamond?

Graphical Image of a nanodiamond
Nanodiamond structure and surface chemistry
TEM Image of Nanodiamonds

Nanodiamonds are one of the most advanced carbon materials in the world.
Diamonds are renowned for their superlative physical qualities such as the highest hardness on earth, superior thermal conductivity to any bulk material, and the high refractive index and abbe number. Nanodiamonds are not only small-sized diamonds with the above features but they also could generate other functions owing to their nano size, various functional groups, high dispersibility, ζ potential, and amorphous carbon.

The structure of nanodiamonds consists of a diamond core and amorphous carbon layers. In more complex terms, each particle of nanodiamonds has sp3 bonded carbon atoms covered by sp2. The most unique feature of nanodiamonds is the existence of various oxygenic functional groups on the surface, thus nanodiamonds have ζ potential in water.
The ζ potential disperses nanodiamonds uniformly and stably in water. Daicel also achieved dispersal of nanodiamonds in various organic solvents such as IPA, THF, MIBK, and Toluene by modifying surface chemicals on nanodiamonds.

Nanodiamonds are produced by a detonation method and the diamonds synthesized are extremely tiny particles with average diameter between 4~6nm. The particles are almost spherical (precisely, polyhedron) unlike abrasive diamonds for lapping, horning and polishing. Because of the size and the shape, a specific surface area of a nanodiamond particle is over 300m2/g.

Nanodiamonds can be used in unique applications compared to other nano materials such as nano-silica, graphene, carbon nanotubes, fullerenes, and carbon nanohorns.
Potential applications of nanodiamonds are break-in additives for lubricants, antioxidants, grain refining agent, bio imaging, drug delivery, diamond sensors, and others. Each function of nanodiamonds in the applications is remarkably unique.

Nanodiamonds can be a game-changing material of the future for those applications, with many products, and potential uses.

Surface Chemistry

There are various oxygenic functional groups on the nanodiamond surface. The main ones are carboxyl, hydroxyl, ketone, and ether. The total number of oxygenic functional groups on a nanodiamond reaches into the hundreds.

The oxygenic functional groups have a high affinity for water and polar organic solvents. On the other hand, they don't have any affinity for oil or nonpolar solvents. Nanodiamonds agglomerate immediately in such media.

Daicel can offer solutions to the problem. Surface chemistries are controllable because of Daicel's organic chemical technology, which makes it possible to realize a rich selection of organic solvent dispersions of nanodiamonds.

The line-up of nanodiamonds will be beneficial to users who hope to mix, disperse in raw materials such as plastics, oils, rubber, metal and others.

Chemically modified nanodiamonds and its applications

ζ potential

Nanodiamonds have ζ potential in dispersions.
The scientific technical term for colloidal dispersion means an electric potential of dispersed particles.
The ζ potential disperses nanodiamonds uniformly and stables in water and some organic polar solvents.

ζ potential of Nanodiamonds

Size

The nanodiamond particle is remarkably small, 4~6nm(four to six billionths of one meter).
The particle size is 20 times smaller than a virus. It is invisible to the naked eye.
A nanodiamond is the smallest diamond but an authentic one.

Size of Nanodiamond

Particle Numbers

There are about 900 quadrillion particles (9×1017) in 1 carat of nanodiamonds.
In cases where surface activity is key to a function, the astronomical particle numbers (and also specific surface area) of monodispersed particles can be beneficial.

Particle number of single diamond per 1carat

Specific Surface Area

One of the greatest properties of nanomaterials is their specific surface area.
Nanodiamonds have far larger surface areas than larger diamonds of equal mass.
When mono-dispersed nanodiamonds are used for applications where it is important to have contact with surrounding materials and create vast interfaces, functions can be maximized.

Comparison of surface area between single diamond and nanodiamonds

Application as Antioxidants

Fundamental Characteristics

Nanodiamonds have unique fundamental characteristics. Each characteristic contributes to applications functions.

Modify Surfaces

Modify Surfaces

One of most typical use of diamonds is abrasives. Nanodiamonds can polish objects and planarize atomically. Furthermore, chemical modification is also conducted by the tiny particles. Friction with nanodiamonds has oxidizability to some materials such as metals and ceramics.

Suppress Degradation

Suppress Degradation

Well dispersed nanodiamonds suppress degradation of engineering plastics, oil and rubber. Basic mechanism of the function is radical scavenging.

Antioxidants

Support Substance

Support Substance

Various chemicals (e.g.fluorescently labeled drugs, medicines, antibodies) can be attached onto nanodiamonds. Many researchers report that nanodiamonds work as drug delivery carriers with high safety to a living body because of the almost spherical shape of nanodiamonds.

Conduct Electricity

Conduct Electricity

Insulators such as plastics and rubber could be turned into electrical conductors by dispersing nanodiamonds into them. (Tunnel effect)

Synthesis Technique of Single Digit Nanodiamonds
(Detonation Method)

Nanodiamonds are produced from explosives by detonation method followed by purification and dispersion processes as below. Daicel Corporation has installed a semicommercial facility for detonation process in our Harima Plant (Hyogo, Japan).
A Diamond structure is formed from carbon atoms in explosives(a mixture of TNT and RDX ) at very high temperature and pressure by detonation in a closed chamber.
Nanodiamonds are originally obtained as aggregates. It is expected that diamond properties will be more prominently expressed when the aggregates are further disintegrated into primary particles. Daicel has developed the single digit nanodiamonds(SDND).

Synthesis Technique of Single Digit Nanodiamonds(Detonation Method)

DINNOVARE

DINNOVARE

Daicel offers eight different types of nanodiamond samples to worldwide researchers. DINNOVARE has cluster NDs and seven different types of solvent dispersions such as ζnegative NDs in water, ζ positive NDs in water, Water-soluble modified NDs in water, and 4 organic solvent dispersions (THF, IPA, MIBK, toluene).

The unique nano-carbon material could be used for various applications, e.g. additives for lubricants, antioxidants, grain refining agent for plating, polishing slurries, bio imaging, drug delivery, and diamond sensors.

For those who are interested in finding new applications of nanodiamonds aside from those mentioned, free DINNOVARE samples are available by giving feedback of outcomes to Daicel.

Product Types Concentration Quantity Solvent Applications
1.Cluster NDs - 1g Powder -
2.ζ-NDs in water 1wt% 50ml Water Water-based lubricants,Biomedical
3.ζ+ NDs in water 1wt% 50ml Water Water-based lubricants,Biomedical
4.Water-soluble modified NDs in water 1wt% 10ml Water Metal plating solutions
5. Monodispersed NDs in THF 1wt% 10ml THF Coartings, Plastics
6. Monodispersed NDs in IPA 1wt% 10ml IPA Electric materials
7.Monodispersed NDs in MIBK 1wt% 10ml MIBK Lubricants
8. Monodispersed NDs in toluene 1wt% 10ml Toluene Lubricants
  • *2Limit two samples per person

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